Oxidative roasting of molybdenite concentrate

A Basic principle The total reaction of molybdenum oxidized roasting is: Reaction is a strong exothermic process

ΔH 298 = 1063kJ/mol

Since many compounds such as MoO 2 and Mo 2 S 3 are present in the Mo-SO system, the reaction is very complicated, and different reactions may occur under different conditions. Please refer to the relevant textbooks.
B Industrial Practice
The main processes and characteristics of molybdenum oxidized roasting are shown in the table:

Main Process and Characteristics of Molybdenum Oxide Roasting

Process name

Product contains sulfur /%

1t molybdenum standard coal consumption / kg

铼 volatilization rate /%

Smoke rate /%

Flue gas SO 2 concentration /%

Recovery rate /%

other

Multi-hearth furnace roasting

≤ 0.1

70~90

40~60

10~20

0.8~3

About 99

Bed energy rate (calculated as molybdenum) 100kg / ( m 2 · d ) is currently the most important industrial method, the product is suitable for both steelmaking and wet processing to prepare molybdenum chemical products or molybdenum

Fluidized furnace roasting

2.0~2.5 (mainly SO 4 2- )

0

About 90

About 40%

3~5

>98

Bed energy rate (calculated as molybdenum) 100kg / ( m 2 · d ), industrial production scale, the product is mainly used in wet chemical products

Rotary kiln

≤ 0.1

400~500

 

 

0.5~4

About 98

For industrial production, life expectancy is about 3~4 months

Reverberatory furnace roasting

≤ 0.1

2000~2200

Can't recycle

 

<1

94~97

For the ancient method, it is still used in China.

Lime sintering

 

 

98 is recovered by Ca ( ReO 4 ) 2

 

 

97~98

Small-scale production, processing mines containing high

Flash roasting

After wet treatment , <0.01

 

 

 

5~10

 

High temperature volatile products contain MoO 3 98%~99.9% , no industrial production reports

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